Crystal structure and electronic properties of 2-amino-2-methyl-1-propanol (AMP) carbamate.
نویسندگان
چکیده
A crystal structure of a carbamate of 2-amino-2-methyl-1-propanol (AMP-carbamate) has been elucidated and its structural and electronic properties investigated by density functional theory calculations and natural bond orbital analyses.
منابع مشابه
On the origin of preferred bicarbonate production from carbon dioxide (CO₂) capture in aqueous 2-amino-2-methyl-1-propanol (AMP).
AMP and its blends are an attractive solvent for CO2 capture, but the underlying reaction mechanisms still remain uncertain. We attempt to elucidate the factors enhancing bicarbonate production in aqueous AMP as compared to MEA which, like most other primary amines, preferentially forms carbamate. According to our predicted reaction energies, AMP and MEA exhibit similar thermodynamic favorabili...
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ورودعنوان ژورنال:
- Chemical communications
دوره 46 48 شماره
صفحات -
تاریخ انتشار 2010